Halp? ._.

So, I'm trying to figure out how to make professional looking websites. My websites made with pure HTML and CSS suck. I'm trying to get into making websites with Dreamweaver and Photoshop, but I can't find any good tutorials on it and I suck with Photoshop =/

So, my question is, is there anyone here who can help me?

Also, who made the layout of the new LG website thing? Now that I've actually been looking at it and not just clicking past it and thinking of it as a nuisance, I noticed that it looks amazing :O